Charvis takes over the captaincy from the injured Scott Quinnell and will also pack down at No 8 in the absence of his fellow 2001 Lions tourist as Wales go in search of their second win of the Championship.
"I am absolutely delighted to have reclaimed my place in the team, getting an opportunity to start was the first priority," said Charvis.
"The extra responsibility of captaincy came more as a surprise and although welcome, must not be allowed to interfere with my playing performance. It's nice to be at the helm, knowing that I am surrounded by so many experienced and capable players. I am confident that as a collective force we can do the nation proud."
Mark Taylor, who last played for Wales virtually a year ago, in the 33-23 victory over Italy in Rome, resumes his Test career after recovering from a knee injury suffered in Australia with the Lions last summer. Taylor, who will win his 31st cap, will form the fourth different midfield partnership Wales have used in the 2002 Championship, Taylor at outside centre to Andy Marinos.
Taylor comes in at the expense of Gareth Thomas as one of the potential six changes National Coach Steve Hansen makes from the team beaten 50-10 by England at Twickenham 11 days ago.
In addition to Charvis for Quinnell and Taylor for Thomas, Rhys Williams is called up on the right wing in place of Dafydd James; Barry Williams takes over from Robin McBryde at hooker and Ian Gough comes in at lock in place of Chris Wyatt. The possible sixth change could see a fit again Stephen Jones back at fly half for Iestyn Harris.
LLOYDS TSB SIX NATIONS CHAMPIONSHIP 2002
WALES v SCOTLAND
Saturday, 6th April
Kick-off: 4.45 pm
15 Kevin Morgan (Swansea)
14 Rhys Williams (Cardiff)
13 Mark Taylor (Swansea)
12 Andy Marinos (Newport Rugby)
11 Craig Morgan (Cardiff)
10 Stephen Jones (Llanelli)/Iestyn Harris (Cardiff)
9 Rob Howley (Cardiff)
1 Iestyn Thomas (Ebbw Vale)
2 Barry Williams (Neath)
3 Chris Anthony (Newport Rugby)
4 Ian Gough (Newport Rugby)
5 Andy Moore (Swansea)
6 Nathan Budgett (Bridgend)
7 Martyn Williams (Cardiff)
8 Colin Charvis (Swansea, captain)
16 Robin McBryde (Llanelli)
17 Spencer John (Cardiff)
18 Chris Wyatt (Llanelli)
19 Gavin Thomas (Bath Rugby)
20 Dwayne Peel (Llanelli)
21 Iestyn Harris (Cardiff)/Stephen Jones (Llanelli)
22 Dafydd James (Bridgend)
REFEREE: Joel Jutge (France)
TOUCH JUDGES: Alan Lewis, Alain Rolland (Ireland)
WRU TV were on hand at the launch of a major new commercial deal with WRU and Mercedes-Benz South Wales (part of the Sinclair Group), which sees the family company become an official supplier to the Welsh Rugby Union
On the back of the recent Women's Rugby World Cup, the WRU has launched a revitalised Women's and Girls domestic seasonal structure, and the future is looking bright.
Go to www.wru.co.uk/tryourgame for more information
Roger Lewis talks to WRU TV at the announcement of a new £60 million Rugby Services Agreement (RSA) which provides a new and positive contractual relationship between the WRU and its four Regions for the next six years has been agreed.
The Welsh Rugby Union has announced a major new sponsorship deal with Gullivers Sports Travel which will make the UK's leading, and longest established, multi-sport tour operator, an Official Supplier for the rest of the decade.
Having taken part in seven World Cups as a player and coach, Liza Burgess hopes to go out in style this afternoon when Wales take on Australia in the Play-off for seventh and eighth place in the Women's Rugby World Cup in Paris.
WRU Head of Rugby Josh Lewsey met with volunteers across the game earlier this week, championing their role in the sport. He was joined by Wales captain Sam Warburton for part of the day as volunteers took part in a 'Try Out' event for the 2015 Rugby World Cup